PHOIBOS 150 NAP MCD

State of the art hemispherical energy analyzer with MCD-9 detector for photoelectron spectroscopy measurements (XPS and UPS) in the pressure regime from UHV to near ambient pressure (NAP)

The PHOIBOS 150 NAP Analyzer is a true 180° hemispherical energy analyzer with 150 mm mean radius. It consists of a differentially pumped electrostatic pre-lens, with a three-stage differentially pumped PHOIBOS 150 analyzer. Thus, the design concept provides four separate pressure stages separated by apertures. The first pumping stage (pre-lens) is separated from the analytic chamber by a nozzle with a customizable opening at the tip with diameters between 0.3 mm and 1 mm. By using a turbopump on the pre-lens stage, a pressure difference of four orders of magnitude (compared to the analysis chamber) can be achieved.The first and second stages are separated by an aperture. An in-lens gate valve allows a high-vacuum seal between of the PHOIBOS 150 Analyzer and NAP pre-lens and enables venting of the analysis chamber and pre-lens without venting the energy analyzer.

For Imaging NAP-XPS the pre-lens can be equipped with the SPECS NAP-XPS Imaging Lens Module that supports two different operation modes, one optimized for lateral resolution and one for transmission. In the lateral resolving mode the acceptance angle can be freely adjusted between +/- 3° to +/- 8° giving an ultimate lateral resolution of better than 10 µm with an acceptance area of 0.6 mm in diameter.

KEY FEATURES

  • Wide Angle Pre-Lens with 44 ° Acceptance Angle
  • Near Ambient Working Pressures up to 100 mbar (depending on configuration)
  • Large pass energy range
  • Working range up to 3.5 keV (upgradeable to 7 keV with corresponding power supply and detector)
  • High energy and angular resolution
  • High spatial resolution with imaging lens module
  • Ultimate flexibility by switching between high transmission and high lateral resolution mode
  • Fast detectors with high dynamic range for fast real time data acquisition in snapshot mode
  • Pneumatic in-lens gate valve
  • 4 differential pumping stages
  • Full detector flexibility (MCD, 1D-DLD, 2D-DLD, 2D-CCD, 2D-CMOS)

R&D100 in 2010
The PHOIBOS 150 NAP Analyzer won the R&D 100 award for the best 100 products developed in 2010.

MADE FOR THESE METHODS

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RELATED PRODUCTS

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APPLICATION NOTES

PUBLICATIONS

  1. (2005) Electron Spectroscopy of Aqueous Solution Interfaces Reveals Surface Enhancement of Halides

    It has been suggested that enhanced anion concentrations at the liquid/vapor interface of airborne saline droplets are important to aerosol reactions in the atmosphere. We report ionic concentrations in the surface of such solutions. Using x-ray photoelectron spectroscopy operating at near ambient pressure, we have measured the composition of the liquid/vapor interface for deliquesced samples of potassium bromide and potassium iodide. In both cases, the surface composition of the saturated solution is enhanced in the halide anion compared with the bulk of the solution. The enhancement of anion concentration is more dramatic for the larger, more polarizable iodide anion. By varying photoelectron kinetic energies, we have obtained depth profiles of the liquid/vapor interface. Our results are in good qualitative agreement with classical molecular dynamics simulations. Quantitative comparison between the experiments and the simulations indicates that the experimental results exhibit more interface enhancement than predicted theoretically.



    S. Ghosal, J. C. Hemminger, H. Bluhm, B. S. Mun, E. L. D. Hebenstreit, G. Ketteler, D. F. Ogletree, F. G. Requejo, M. Salmeron
    Science 307, pp. 563 - 566
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  2. (2005) High-Pressure X-ray photoelectron spectroscopy of palladium model hydrogenation catalysts. Part 1: Effect of gas ambient and temperature

    In light of accumulating evidence highlighting the major effect of operational conditions (gas composition, pressure, temperature) on the surface/bulk structure of catalytic materials, their characterization should involve more and more in situ methods. We constructed a synchrotron-based high-pressure X-ray photoelectron spectroscopic (XPS) instrument, allowing us to investigate the surface and near-surface state of a catalyst in the mbar pressure range. We discuss here the surface characteristics of palladium samples as a function of gas phase (hydrogen, oxygen) and temperature. We demonstrate that the surface region of catalytic materials behaves dynamically in its composition, always reflecting its environment. For example, surface oxide can be formed on Pd(111) in oxygen, which decomposes rapidly when the gas supply is switched off. The chemical nature of carbonaceous deposits also depends strongly on the operational conditions (gas-phase hydrogen, temperature). This is the first time that an XPS investigation of palladium β-hydride was performed at RT. The possible drawbacks of using a non-UHV setup (e.g., fast carbon accumulation) are also discussed.



    D. Teschner, A. Pestryakov, E. Kleimenov, M. Hävecker, H. Bluhm, H. Sauer, A. Knop-Gericke, R. Schlögl
    Journal of Catalysis 230, pp. 186 - 194
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  3. (2005) In Situ Spectroscopic Study of the Oxidation and Reduction of Pd(111)

    Using a photoemission spectroscometer that operates close to ambient conditions of pressure and temperature we have determined the Pd−O phase diagram and the kinetic parameters of phase transformations. We found that on the (111) surface oxidation proceeds by formation of stable and metastable structures. As the chemical potential of O2 increases chemisorbed oxygen forms followed by a thin surface oxide. Bulk oxidation is a two-step process that starts with the metastable growth of the surface oxide into the bulk, followed by a first-order transformation to PdO.



    G. Ketteler, D. F. Ogletree, H. Bluhm, H. Liu, E. L. D. Hebenstreit, M. Salmeron
    J. Am. Chem. Soc. 127 (51), pp. 18269–18273
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  4. (2005) Soft X-ray microscopy and spectroscopy at the molecular environmental science beamline at the Advanced Light Source

    We present examples of the application of synchrotron-based spectroscopies and microscopies to environmentally relevant samples. The experiments were performed at the molecular environmental science beamline (11.0.2) at the Advanced Light Source, Lawrence Berkeley National Laboratory. Examples range from the study of water monolayers on Pt(1 1 1) single crystal surfaces using X-ray emission spectroscopy and the examination of alkali halide solution/water vapor interfaces using ambient pressure photoemission spectroscopy, to the investigation of actinides, river water biofilms, Al-containing colloids and mineral–bacteria suspensions using scanning transmission X-ray spectromicroscopy. The results of our experiments show that spectroscopy and microscopy in the soft X-ray energy range are excellent tools for the investigation of environmentally relevant samples under realistic conditions, i.e., with water or water vapor present at ambient temperature.



    H. Bluhm, K. Andersson, T. Araki, K. Benzerara, G. E. Brown, J. J. Dynes, S. Ghosal, M. K. Gilles, H.-Ch. Hansen, J. C. Hemmingerf, A. P. Hitchcock, G. Ketteler, A. L. D. Kilcoyne , E. Kneedler , J.R . Lawrence , G. G. Leppard , J. Majzlam , B. S. Munl, S
    Journal of Electron Spectroscopy and Related Phenomena 150, pp. 86-104
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  5. (2005) XPS investigations of VPO catalysts under reaction Conditions

    The surface of vanadium phosphorus oxide (VPO) catalysts was investigated by (in situ) X-ray photoelectron spectroscopy (XPS) under reaction conditions. Two differently prepared VPO samples with similar catalytic activities showed different spectral behaviour while the catalytic conditions were changed. The vanadium surface oxidation state of both catalysts was found to have the same value close to 4 under reaction conditions, while the oxidation state of vanadium in deeper layers differed significantly. The experimental results suggest that in VPO the catalytically active species located in the topmost surface layers (up to 1 nm depth) are only weakly related to the structure of deeper layers. Based on our results we suggest that the deeper layers act as a substrate material only and can be different from the surface.



    E. Kleimenov, H. Bluhm, M. Hävecker, A. Knop-Gericke, A. Pestryakov, D. Teschner, J. A. Lopez-Sanchez, J. K Bartley, G. J. Hutchings, R. Schlögl
    Surface Science 575 (1-2), pp. 181-188
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